Online monitoring of the reactions of 2-cyanobenzaldehyde with carbanions derived from ethyl 2-arylacetates

Zitation: Thiruvengetam, Prabaharan und Ofial, Armin: Online monitoring of the reactions of 2-cyanobenzaldehyde with carbanions derived from ethyl 2-arylacetates. 4. März 2026. Open Data LMU. 10.5282/ubm/data.784

Be­schrei­bung

The reactions of deprotonated ethyl 2-arylacetates (aryl = p-nitrophenyl or p-cyanophenyl) with 2-cyanobenzaldehydes in DMSO at 20 °C were monitored by stopped-flow photometry. The zip file contains txt files with absorbance vs. time data; exp files used for the k(obs) determination; pdf files with results of the k(obs) determination. Folder names PTxxx refer to individual series of experiments and are identical to those in the Supporting Information (docx/rtf/pdf).

Stichwörter

kinetics, reactivity, time-resolved spectroscopy

• Dokumententyp: Daten
• Name der Kontakt­person: Ofial, Armin
• E-Mail der Kontaktperson: ofial at lmu.de
• URL der Kontaktperson: https://ofial.cup.uni-muenchen.de
• Fächer: Chemie und Pharmazie
• Dewey Dezimal­klassi­fikation: 500 Naturwissenschaften und Mathematik ; 500 Naturwissenschaften und Mathematik > 540 Chemie
• Eingestellt von: Dr. Armin Ofial