Readme for the documentation of scientific data sets

Author Readme:				Ofial; Armin

Date of creation Readme:		2025-03-04
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Title of the scientific data set:	Online monitoring of the reactions of 2-cyanobenzaldehyde with carbanions derived from ethyl 2-arylacetates

Version:				1.0

Contact:				Ofial, Armin; Dept. Chemistry, LMU Muenchen, Germany; ofial@lmu.de

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Author 1 of scientific data set:	Thiruvengetam; Prabaharan
Author 1 Identifier:			https://orcid.org/0000-0003-3845-8490
Author 1 Affiliation:			Dept. Chemistry, LMU Muenchen, Germany
Author 1 Contribution:			Researcher, DataCurator


Author 2 of scientific data set:	Ofial; Armin R.
Author 2 Identifier:			https://orcid.org/0000-0002-9600-2793
Author 2 Affiliation::			Dept. Chemistry, LMU Muenchen, Germany
Author 2 Contribution:			ContactPerson, ProjectLeader, DataCurator

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Project name:				Cascade reactions with 2-cyanobenzaldehydes for the synthesis of 3-substituted isoindolinones

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Abstract:				The reactions of deprotonated ethyl 2-arylacetates (aryl = p-nitrophenyl or p-cyanophenyl) with 2-cyanobenzaldehydes in DMSO at 20 °C were monitored by stopped-flow photometry. 
					Folder names PT116 (aryl = p-cyanophenyl) and PT117 (aryl = p-nitrophenyl) refer to the individual series of experiments and are identical to those in the Supporting Information files "OpenData_SI_OnlineMonitoring.docx/pdf/rtf".

Keywords:				kinetics, reactivity, nucleophiles, time-resolved spectroscopy

Methods for data collection: 		time-dependent photometric measurements
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File list:				The zip file contains 
					txt files with absorbance vs. time data; exp files used for the k(obs) determination; pdf files with results of the k(obs) determination.  

File formats: 				*.txt (raw data), *.exp (evaluated data), *.pdf (evaluated data, Supporting Information), *.docx (Supporting Information), *.rtf (Supporting Information).

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Remarks: 				This project has received funding from the European Union's Horizon Europe research and innovation programme under the Marie Sklodowska-Curie grant agreement No. 101106557 "ResolveByBio" (MSCA-2022-PF to P.T.).