Reactivity of N-Boc-3-nitro-7-azaindole: adduct characterization and kinetics of the reactions with carbanions

Citation: Zhang, Tianyu and Ofial, Armin: Reactivity of N-Boc-3-nitro-7-azaindole: adduct characterization and kinetics of the reactions with carbanions. 12. May 2026. Open Data LMU. 10.5282/ubm/data.813

Abstract

The zip file contains the main folders (1) 'analytics' and (2) 'kinetics' (1) ‘analytics’ Subfolders contain raw and evaluated analytics data for the Wheland σ-complexes, which were characterized (UV-Vis, HRMS and NMR) in d6-DMSO solution. (2) 'kinetics' Subfolders ‘EDA 11a + 12 ….’ contain *.txt files with absorbance vs. time data [raw data] *.exp files used for the kobs determination [evaluated data] *.pdf files with results of the kobs determination [evaluated data]. Compound labels (that is, 11a for the electrophile N-Boc-3-nitro-7-azaindole and 12a–12h for the nucleophilic carbanions) are identical to those in this Supporting Information.

Uncontrolled Keywords

Kinetics, Reactivity, Electrophiles, Time-resolved spectroscopy

• Item Type: Data
• Contact Person: Ofial, Armin
• E-Mail of Contact: ofial at lmu.de
• URL of Contact: https://ofial.cup.uni-muenchen.de
• Subjects: Chemistry and Pharmacy
• Dewey Decimal Classification: 500 Natural sciences and mathematics; 500 Natural sciences and mathematics > 540 Chemistry and allied sciences