Reactivity of N-Boc-3-nitro-7-azaindole: adduct characterization and kinetics of the reactions with carbanions

Zitation: Zhang, Tianyu und Ofial, Armin: Reactivity of N-Boc-3-nitro-7-azaindole: adduct characterization and kinetics of the reactions with carbanions. 12. Mai 2026. Open Data LMU. 10.5282/ubm/data.813

Be­schrei­bung

The zip file contains the main folders (1) 'analytics' and (2) 'kinetics' (1) ‘analytics’ Subfolders contain raw and evaluated analytics data for the Wheland σ-complexes, which were characterized (UV-Vis, HRMS and NMR) in d6-DMSO solution. (2) 'kinetics' Subfolders ‘EDA 11a + 12 ….’ contain *.txt files with absorbance vs. time data [raw data] *.exp files used for the kobs determination [evaluated data] *.pdf files with results of the kobs determination [evaluated data]. Compound labels (that is, 11a for the electrophile N-Boc-3-nitro-7-azaindole and 12a–12h for the nucleophilic carbanions) are identical to those in this Supporting Information.

Stichwörter

Kinetics, Reactivity, Electrophiles, Time-resolved spectroscopy

• Dokumententyp: Daten
• Name der Kontakt­person: Ofial, Armin
• E-Mail der Kontaktperson: ofial at lmu.de
• URL der Kontaktperson: https://ofial.cup.uni-muenchen.de
• Fächer: Chemie und Pharmazie
• Dewey Dezimal­klassi­fikation: 500 Naturwissenschaften und Mathematik ; 500 Naturwissenschaften und Mathematik > 540 Chemie
• Eingestellt von: Dr. Armin Ofial