Kinetic measurements and product studies used to determine the nucleophilicity of α-aryl vinyl azides

Citation: Thiruvengetam, Prabaharan and Gross, Christoph and Ofial, Armin: Kinetic measurements and product studies used to determine the nucleophilicity of α-aryl vinyl azides. 29. December 2025. Open Data LMU. 10.5282/ubm/data.761

Abstract

The zip file contains (1) a folder named "kinetics", which contains txt files with absorbance vs. time data; exp files used for the k(obs) determination; pdf files with results of the k(obs) determination. Folder and file names CGxxx and PTxxx refer to individual experiments and are identical to those in the Supporting Information (docx/rtf/pdf). (2) a folder named "products" which contains analytical data (NMR, IR, and HRMS) used to characterize the synthetically prepared vinyl azides as well as the amides isolated from the reactions of vinyl azides with benzhydrylium ions. Folder and file names CGxxx and PTxxx for the characterized chemical compounds are identical to those in the Supporting Information (docx/rtf/pdf).

Uncontrolled Keywords

kinetics, product characterization, nucleophiles, time-resolved spectroscopy

• Item Type: Data
• Contact Person: Ofial, Armin
• E-Mail of Contact: ofial at lmu.de
• URL of Contact: https://ofial.cup.uni-muenchen.de/
• Subjects: Chemistry and Pharmacy
• Dewey Decimal Classification: 500 Natural sciences and mathematics > 540 Chemistry and allied sciences